Evaluation of Synthesized S, N-CQDS/ZNCo2O4 Heterojunction Nanocomposite as an Efficient Photocatalytic Decolourisation of Organic Pollutants under Visible Light Irradiation
Author Affiliations
- 1Department of Photochemistry, Govt. Madhav Science P.G. College, Ujjain, M.P., India
- 2Department of Photochemistry, Govt. Madhav Science P.G. College, Ujjain, M.P., India
Res.J.chem.sci., Volume 16, Issue (3), Pages 13-17, October,18 (2026)
Abstract
New synthesized materials exhibit promising applications as photocatalysts for ecological rehab and better usage of non-conventional energy source i.e. Sun. Semiconductor-based photocatalysts have been massively utilized for the overall elimination or fading of organic pollutants from wastewater in the presence of solar light irradiation. The heterojunction photocatalyst was synthesized by decorating S, N-CQDs onto the surface of ZnCo2O4 nanomaterials. The structural and morphological features of the developed material were analysed using powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and energy–dispersive X-ray spectroscopy (EDX) analyses. It was found that the morphology of the prepared sample was spherical in shape. The EDX-Spectrum of the nanocomposite revealed the existence of Zn, Co and O elements. The photocatalytic activity of the prepared catalyst was evaluated for the degradation calmagite dye an organic dye was found to be 85% after 90 min of solar light irradiation.
References
- Zhou, Q., Yang N., Li Y., Ren B., Ding X., Bian H., Yao X. (2020)., Total concentrations and sources of heavy metal pollution in global river and lake water bodies from 1972 to 2017., Glab. Ecol. Conser, 22, 925.
- Elsalamony R. A. (2016)., Advances in photo-catalytic materials for environmental applications., Res. Rev. J. Mat. Sci., 4, 26–50.
- Khan M. M., Adil, S. F. and Al-Mayouf A. (2015)., Metal oxides as photocatalysts., J. Saudi Chem. Soc., 19, 462–464.
- Jung J., Jang J.W. and Park W. (2016)., Effect of generation growth on photocatalytic activity of nano TiO2-magnetic cored dendrimers., J. Ind. Eng. Chem., 44, 52–59.
- Abdelbasir S. M. and Shalan A. E. (2019)., An overview of nanomaterials for industrial wastewater treatment, Korean., J. Chem Eng., 36, 1209–1225.
- Bodzek M., Konieczny K. and Kwiecińska-Mydlak A. (2020)., Nanotechnology in water and wastewater treatment. Graphene the nanomaterial for next generation of semipermeable membranes, Environ. Sci. Technol., 50, 1515-1579.
- Yu H., Zhao H., Wu Y. and Chen B. (2020)., Electrospun ZnCo2O4/C composite nanofibers with superior electrochemical performance for supercapacitor, J. Phy. Chem. Solid, 140,109385.
- Zhou J., Ding J., Wan H. and Guan G. (2021)., Boosting photocatalytic decolourisation of antibiotic wastewater by synergy effect of heterojunction and phosphorus doping, J. Colloid Inter. Sci., 582, 961-968.
- Pare B., Barde V.S., Solanki V.S., Agarwal N., Yadav V.K., Alam M.M., Gacem A., Khedher N.B., Park J.W. and Jeon B.H. (2022)., Green Synthesis and Characterization of LED- Irradiation-Reaponsive Nano ZnO Catalyst and Photocatalytic Mineralization of Malachite Green Dye., Water, 14(20), 3221.
- He S., Zhang C., Du C., Cheng C. and Chen W. (2019)., High-rate-performance supercapacitor based on nitrogen-doped hollow hexagonal carbon nanoprism arrays with ultrathin wall thickness in situ fabricated on carbon cloth, J. Power Sources, 434, 226701.
- Tantubay K., Das P. and Baskey M. (2022)., Hydrogen peroxide assisted photocatalytic dye decolourisation over reduced graphene oxide integrated ZnCr2O4 nanoparticles., Environ. Sci. Pollut. Res., 29, 17309-17318.
- Narasimharao K., Mustafa M.M., Al-Amshany Z.M. and Bajaf W. (2023)., Mechanochemical Synthesized CaO/ ZnCo2O4 Nanocomposites for Biodiesel Production, Catalysts., 13, 398.
- Cruz N.D., Esplugas S., Grandjiean, D., Alencastro, L.F. and Pulgarin C. (2012)., Decolourisation of emergent contaminants by UV and neutral photo-fenton in domestic wastewater effluent previously treated by activated sludge., Water Res., 6, 1947-1957.
- Zhang J.H., Zou H.Y., Ning X.A., Lin M.Q., Chen C.M., An T.C. and Sun J. (2018)., Combined ultrasound with fenton treatment for the decolourisation of carcinogenic polycyclic aromatic hydrocarbons in textile dying sludge, Environ. Geochem. Health, 40, 1867-1876.
- Babuponnusami A. and Muthukumar K. (2013)., A review on Fenton and improvements to the Fenton process for wastewater treatment, J. Environ. Chem. Eng., 2, 557–572.
- Shi W., Fang W. X., Wang J.C., Qiao X., Wang B. and Guo X. (2021)., pH-controlled mechanism of photocatalytic RhB decolourisation over g-C3N4 under sunlight irradiation., Photochem. Photobiol Sci., 20, 303-313.
- Verma S., Rao B.T., Singh R. and Kaul R. (2021)., Photocatalytic decolourisation kinetics of cationic and anionic dyes using Au-ZnO nanorods: Role of pH for selective and simultaneous decolourisation of binary dye mixtures., Ceramic. Inter., 47, 34751-34764.
- Jia K., Liu G., Lang D., Chen S., Yang C., Wang W. and Wang J., (2022)., Fast photodecolourisation of antibiotics and dyes by an anionic surfactant-aided CdS/ZnO nanodispersion., New J. Chem., 23, 11303-11314.
- Chen R., Zhu C., Lu J., Xiao J., Lei Y. and Yu Z. (2018)., BiVO4/α-Fe2O3 catalytic decolourisation of gaseous benzene: preparation, characterization and photocatalytic properties., Appl. Surf. Sci., 427, 141–147.
- Chai Y.Y., Qu D.P., Ma D.K., Chen W. and Huang S. (2018)., Carbon quantum dots/Zn2+ ions doped-CdS nanowires with enhanced photocatalytic activity for reduction of 4-nitroaniline to phenylenediamine., Appl. Surf. Sci., 450, 1-8.
- Xu L., Li H.M., Xu H. and Lian J.B. (2017)., Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density, Energy, 123, 296-304.
- Kanakaraju D., Yahya M.S. and Wong S.P. (2019)., Removal of chemical oxygen demand from agro effluent by ZnO photocatalysis and photo- Fenton, App. Sci., 7, 738.
