Sputtering of metal Nanoparticles in Polymer film to create multiple Properties in the Nanocomposite System
Author Affiliations
- 1Nanoscience and Nanotechnology Laboratory, School of Physics, Devi Ahilya University, Vigyan Bhawan, Takshila Campus, Khandwa Road, Indore, 452001, India
- 2Defence Research & Development Organization (DRDO), DMSRDE, Kanpur, 208013, India
- 3Nanoscience and Nanotechnology Laboratory, School of Physics, Devi Ahilya University, Vigyan Bhawan, Takshila Campus, Khandwa Road, Indore, 452001, India
Res. J. Recent Sci., Volume 14, Issue (2), Pages 11-17, April,2 (2025)
Abstract
Iron (Fe) nanoparticles were embedded in Poly methyl methacrylate (PMMA) film using ion beam sputtering (IBS) technique. The GIXRD pattern of the as-prepared PMMA/Fe nanocomposite film showed the presence of Fe in metallic state with BCC phase in the nanocomposite. The MOKE magnetometer record reveals the ferromagnetic nature of such nanocomposite. AFM study shows evenly dispersed Fe nanoparticles. The UV-VIS spectroscopic studies showed that on incorporation of Fe nanoparticles, the % transmission decreased drastically, band gap got reduced but the refractive index, dielectric constant and optical conductivity increased. The results are described in the paper.
References
- Naka, K., Itoh, H., Park, S. Y., and Chujo, Y. (2004)., Synthesis of nanocomposites of metal nanoparticles utilizing miscible polymers., Polymer Bulletin, 52, 171-176.
- Ghosh, P. and Mukherjee, G.S. (1999)., Photopolymers (I): photo initiating role of monochloroacetic acid in the synthesis of poly (methyl methacrylate)., Polym. Adv. Technol, 10, 687-694.
- Mukherjee, G. S., Saraf, M. N., Gupta, R. K., and Vishwanath, B., (1990)., Glass microsphere filled epoxy syntactic foam for radome., J. Polym. Mater., 7, 203-208.
- Jayalakshmi, C. G., Inamdar, A., Anand, A., Kandasubramanian, B. (2019)., Polymer matrix composites as broadband radar absorbing structures for stealth aircrafts., J. Appl. Polym. Sci., 136, 47241.
- Millan,A., Palacio,F., Falqui, A., Etienne, A. & Serin, V., (2002)., Particle size and density control in magnetic polymer Nanocomposites., MRS Online Proceedings Library 733(2).
- Du, H., Xu, G. Q., Chin, W.S., Huang, L., and Ji, W., (2002)., Synthesis, Characterization, and Nonlinear Optical Properties of Hybridized CdS-Polystyrene nanocomposites., Chem. Mater., 14 (10), 4473.
- McCarley, R. L., Vaidya, B., Wei, S., Smith, A. F., Patel, A. B., Feng, J., Murphy, M.C., and Soper, S.A., (2005), Resist-free Patterning of Surface Architectures in Polymer-based Microanalytical Devices., Am. Chem. Soc.,127, 842.
- Joshi, A., Mukherjee, G.S., Gupta, M., Banerjee, M. (2023),, Thickness dependent microstructural and magnetic studies of iron embedded PVA nanocomposite films., AIP Advances, 13, 035339.
- Choudhary, A., Banerjee, M, Mukherjee, G.S. and Joshi, A., (2019)., Magnetic and structural properties of poly methyl methacrylate (PMMA)/Fe film., AIP Conference Proceedings, 2100, 020181,
- Nagar, S., Mukherjee, G.S., Banerjee, M. (2024)., Studies on the structural and magnetic properties of PMMA/Ni nanocomposite system prepared by embedding Ni nanoparticles in the PMMA films., Materials Chemistry and Physics, 314, 128913.
- Nagar, S., Mukherjee, G.S., Banerjee, M., (2023)., Structural and Magnetic Properties of Ni Nanoparticles Embedded in Vinyl Polymer Nanocomposite Films., SPIN, 13(2), 234001.
- Sachdev, P., Banerjee, M., Mukherjee, G.S., (2014)., Magnetic and Microstructural Studies on PVA/Co Nanocomposite Prepared by Ion Beam Sputtering Technique., Defence Science Journal, 64(3), 290-294.
- Chen, M., Yamamuro, S., Farrell D. and Majetich, S.A., (2003)., Gold- coated iron nanoparticles for biomedical application., J. Appl. Phys., 93(10), 7551-7553.
- Berry, C. C., and Curtis, A.S.G., (2003)., Functionalisation of magnetic nanoparticles for applications in biomedicine., J. Phys. D: Appl. Phys., 36 (13), R198-R206.
- Berry, C. C. (2005)., Possible exploitation of magnetic nanoparticle–cell interaction for biomedical applications., J. Mater. Chem., 15, 543-547.
- Devikala, S., Kamaraj, P. and Arthanareeswari, M., (2013),, Conductivity and dielctric studies of PMMA components., Chem Sci Trans., S129-S1342.
- Abd El-Mongy, S., Mohammed, M. I., Yahia, I. S., (2020)., Preparation and spectroscopic studies of PbI2-doped poly (methyl methacrylate) nanocomposites films: Dielectric and optical limiting approach., Optical Materials, 100, 109626.
- Choudhary, A., Mukherjee, G. S., Banerjee, M. and Nagar, S. (2020)., Studies on structural and magnetic properties of PMMA/Co/Ag nanocomposite film., AIP Conf. Proc., 2220, 020075.
- Gheorghe, N. G., Husanu, M. A., Lungu, G.A., Costescu, R.M., Macovei, D.,Popescu, D.G., Teodorescu., C.M., (2012)., Reactivity, Magnetism And Local Atomic Structure in Ferromagnetic Fe Layers Deposited On Si(001)., Digest material of nanomaterial and bio structure, 7 (1), 373- 384.
- Banerjee, M., Jain, A. and Mukherjee, G.S. (2018),, Spectroscopic Evaluation of Optical Parameters of a Transition Metal Salt Filled Polymer Material., Defence Science Journal, 68(2), 225-231.
- Banerjee, M., Jain, A., and Mukherjee, G.S., (2018),, Microstructural and Optical Properties of Polyvinyl Alcohol/Manganese Chloride Composite Film Polymer Composites., 1-11.
- Banerjee, M., Sachdev, P., Joshi, A., Chaudhary, A., Nagar, S., and Mukherjee, G.S., (2024)., Synthesis and characterization of polymer/metal nanocomposite magnetic materials, “Foundation and Growth of Macromolecular Science: Advances in Research for Sustainable Development”., Published by Taylor and Francis, CRC Press and Apple academic publishers. (Eds.) M. S. Mathew, Józef T. Haponiuk and Sabu Thomas, pp. 97-110.
- Ghosh, P., and Mukherjee, G.S., (1989)., Comparative kinetics of photopolymerization of methyl methacrylate using chloro derivatives of acetic acid in combination with dimethylanilline as photoinitiators., European Polymer Journal, 25(10), 1049-1053.