Spectrophotometric Method for determination of Copper (II) using pChlorobenzaldehyde-4-(2’-carboxy-5-sulphophenyl)-3-thiosemicarbazone [p-CBCST]
Author Affiliations
- 1Department of Chemistry, SIR P. T. Sarvajanik College of Science, Surat-395009, INDIA
Res.J.chem.sci., Volume 4, Issue (2), Pages 1-6, February,18 (2014)
Abstract
p-Chlorobenzaldehyde-4-(2’-carboxy-5’-sulphophenyl)-3-thiosemicarbazone [p-CBCST] is spectrophotometric reagent for copper (II) in DMF. Reaction between metal ion and p- Chlorobenzaldehyde -4-(2’-carboxy-5’-sulphophenyl)-3-thiosemicarbazone [p-CBCST] forming a pale yellow colored complex in the pH range 3.0-4.5. The complex shows maximum absorption at 325 nm. The molar absorptivity found to be 5.137×103 lit. mol.-1 cm.-1. The complexes have been characterized on the basis of elemental analysis, UV, IR, NMR spectra. p-CBCST is found to be a selective and strong chelating agent for copper. The 1:2 metal:ligand ratio of complex found from the mole ratio and the slope ratio method and the Job’s method of continuous variation. The stability constant of the complex found to be 1.184 × 112.
References
- Stankoviansky S., Carsky S.J. and Beno A., New Spectrophotometric Method for Determination of Cadmium, Chim Zvesti., 23, 589 (1979)
- Reddy K.G., Reddy K.H., Reddy D.V, Indian J. Chem., 25A, 982 (1986)
- Singh R.B., Garg B.S., Singh R.P., Analytical applications of thiosemicarbazones and semicarbazones: A review, Talanta,25(11-12), 619-632 (1978)
- Patel B.H., Shah J.R., Patel R.P., J. Ind. Chem. Soc.; 539 (1976)
- Vogel A.I., A Text Book of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis, The English Language Book Society and Longman, London, 3rd Ed, 802, (1968)
- Ezhilarasi et al., Synthesis Characterization and Application of Salicylaldehyde Thiosemicarbazone and Its Metal Complexes, Int. J. Res. Chem. Environ.,2(4), 130-148 (2012)
- Giorgio Pelosi, Thiosemicarbazone Metal Complexes: From Structure to Activity, the Open Crystallography Journal, 16-28 (2010)
- Seena E.B., Bessy Raj., M. R Prathapachandra Kurup., Suresh I.E., A crystallographic study of 2-hydroxyacetophenone N (4) cyclohexyl thiosemicarbazone, J. Chem. Crystallogr., 36, 189 (2006)
- Pan K., Scott M.K., Lee D.H.S., Fitzpatrick L.J., Crooke J.J., Riverno R.A., Rosenthal D.I., Vaidya A.H., Zhao, B., Reiz A.B., Bioorg Med Chem, 11, 185 (2003)
- Ainscoegh E.W., Brodie A.M., Ranford H.D., Waters J.M., J Chem Soc Dalton Trans, 1, 2125 (1991)
- French F.A. and Blanz E.J., J Cancer Res, 26, 1638, (1996)
- Kasuga N.C., Sekino K., Ishikawa M., Honda A., Yokoyama M., Nakano S., Shimada N., Koumo C. and Nomiya K., J Inorg Biochem, 96, 298 (2003)
- Afrasiabi Z., Cinn E., Chen J.N., Ma Y.F., Rheingold A.L., Zakharov L.N., Rath N. and Padhye S., Inorg Chim Acta, 357, 271 (2004)
- Sau D.K., Butcher R.J., Chaudhupi S., Saha N., Mol Cell Biochem, 253, 21 (2000)
- Easmon J., Purstinger G., Heinisch G., Roth T., Fiebig H.H., Holzer W., Jager W., Jenny M., Hofmann J., J Med Chem,44, 2164 (2001)
- Kovala-Demeptzi D., Demdrtzis M.A., Miller J.R., Fbampton C.S., Jasinski J.P., West D.X., J Inorg Biochem, 92, 137 (2002)
- Chandra B.S. and Tyagi M., Spectroscopic and biochemical studies of chromium (III) and manganese (II) complexes with -vanillin containing thiosemicarbazone and semicarbazone ligands, J. Indian Chem. Soc., 85, 42-47 (2008)
- Chaudhary Rakhi and shelly,Synthesis, Spectral and Pharmacological Study of Cu (II), Ni (II) and Co (II) Coordination Complexes, Res. J. chem. Sci., 1(5), 1-5 (2011)
- Nagajothi A., Kiruthika A., Chitra S. and Parameswari K., Fe(III) Complexes with Schiff base Ligands: Synthesis, Characterization, Antimicrobial Studies, Res. J. chem. Sci., 3(2), 35-43, (2013)
- Raymond P., Peter P.R., Rajendran S. and Manivannan M., Investigation of corrosion inhibition of stainless steel by sodium tungstate patric, Res. J. Chem. Sci., 3(2), 54-58 (2013)
- Tetsumi T., Sumi M., Taraka M. and Shono T., Direct reaction of metal powders with several sodium dithiovarbamates, Polyhedron, 5(3), 707 (1986)
- Buttrus N.H. and Mohamed S.M., Synthesis and Characterization of Ni+2, Cu+2 and Zn+2 complexes with Benzoxazole-2-thionate, Diphenyl Phosphinomethane and Iodine, Res. J. Chem. Sci., 3(6), 54-59 (2013)
- Patel N.C., Patel I.J., Complexes of Cu(II), Ni(II),Hg(II) and Co(II) with Acetophenone-4-(2’-carboxy-5’-sulphophenyl)-3-Thiosemicarbazone, J. Inst chemists (India),68, Part 5, (1996)
- Desai N.C., Parekh B.R. and Thaker K.A., J. Indian chem. soc., 66, 344 (1989)
- Patel N.C., M. Phil. Dissertation.,(1994)
- Job P., Ann. Chem., 115, 332 (1938)
- Yoe J.H. and Jones A.L., Colorimetric Determination of Iron with Disodium-1, 2-dihydroxybenzene-3, 5- disulfonate, Ind. Eng. Chem. Anal. Ed., 16(2), 111-115, (1944) DOI: 10.1021/i560126a015
- Campbell K.J.M., Grzeskowiask R.J., Some copper (II) complexes of thiosemicarbazide, J. Chem. Soc. A, 396-401, (1967), DOI: 10.1039/J19670000396,
- Dyer J.R., Application of Absorption Spectroscopy to Organic compounds, Prentice Hall of India Private Ltd., New Delhi (1994)
- Ram Reddy M.G., J. Indian chem. Soc., 76, 498-499 (1999)
- Boyle james V., Fheranc Marilyn E. and Richard W. Ross, Jr., Antimicrob AgentsChemother., 3(3), 418–424, (1973)
- Elemike E.E., Oviawe A.P., Otuokere I.E., Potentiation of the Antimicrobial Activity of 4-Benzylimino-2, 3-Dimethyl-1-Phenylpyrazal-5-One by Metal Chelation, Res. J. chem. Sci., 1(8), 6-11 (2011)