Eco friendly Novel Polymers based on Glycerol and Sorbitol as a Subtitutes of Acid Slurry in Detergents
Author Affiliations
- 1Laxminarayan Institute of Technology R.T.M. Nagpur University Nagpur, MH, INDIA
Res.J.chem.sci., Volume 4, Issue (11), Pages 39-44, November,18 (2014)
Abstract
Polymeric surfactants based on glycerol and sorbitol have been synthesized and used successfully in detergent compositions.In the present research work a small quantity of maleic anhydride, phthalic anhydride and citric acid along with major quantity of glycerol and sorbitol have been used in synthesis of polymers. The synthesized polymers have been analyses for their physicochemical characteristics like acid value, % oxirane oxygen, HLB ratio, cleaning efficiency and spectral properties like I.R. and N.M.R spectra. Selected novel polymeric surfactants based on these observations have been used in the preparation of powder detergent compositions. In progressive formulations acid slurry of petroleum origin has been replaced by novel polymer by 20-100 %. The total replacement of acid slurry with novel polymer is viable without affecting foaming, cleaning and stain removing capacity.
References
- Garrett H.E., Surface Active Chemicals Programmer Press, New York (1972)
- Encyclopedia of Chemical Technology, 20, John Wiley and Sons, New York, 750, (1982)
- Harris J.C., Detergency Evaluation and Testing Intors Science Publisher in, New York (1984)
- A STM Standard Method 6.01, dl 639.70 (for acid value) of Organic Coating Material, Published by the American Society for Testing Material, Philadelphia(1981)
- Dakite P.A., Gogte B.B. and Phate B.W., Int. J. Chem. Sci., 9(2), 816-824 (2011)
- Gogte B.B. and Bhagwat A.M., J. Soaps Deter. Toilet Rev,36, 20-25 (2004)
- Puri B.R. and Sharma I.R., Principals of Physical Chemistry, S.chandandco, New Delhi (1997)
- Silverstein R.M. and Webrster F.X, Spectroscopic identification of Organic Compound, 6th edition to JohnWilley and Sons, inc., New York, 71-143, 217-250 (1998)
- Payne H.F., Organic Coatings Technology, vol.I, John willy and Sons, New York, 87- 106 (1961)
- Harris J.C, Detergency evaluation and Testing (Inter sciences Publisher, Inc,New York 1954)
- Gogte B.B. , Agrawal R. S., Detergent formulations Based on artificial neural network, J. Chemical Engg World.38, 80 (2003)
- IS: 5785, Methods for performance tests for surfaceactive agents. Part IV (Indian standards. New Delhi), (1976)
- BIS: 4955, Methods for the test of detergency for house hold detergents (2000)