International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN. 

Study on the Yield and Physicochemical Properties of Oils from Ethiopian Castor Seed (Ricinus communis L.) Varieties and Biodiesel Production

Author Affiliations

  • 1Department of Plant Science, College of Agriculture, Hawassa University, Ethiopia
  • 2Department of Chemistry, College of Computational and Natural Science, Hawassa University
  • 3Department of Plant Science, College of Agriculture, Hawassa University, Ethiopia
  • 4Department of Food Science, College of Agriculture, Hawassa University, Ethiopia

Res.J.chem.sci., Volume 16, Issue (1), Pages 24-38, February,18 (2026)

Abstract

Castor seed is one of the seeds with an untapped potential for its oil for biofuel production. The aim of this study was to compare the yield and physicochemical characteristics of oils produced from two varieties of Ethiopian castor seed varieties (HIRUY and ABARO) and to evaluate the methyl ester profile of these oils for the production of biofuels. Soxhlet and screw press methods were used with a factorial of 2X2 for the evaluation of the oil yield and the physicochemical properties. This finding showed that the oil yield is significantly influenced by the interaction between the variety and the method of extraction. A higher oil yield (56.693%) was obtained from the HIRUY variety by the Soxhlet extraction method and a lower oil yield (42.06%) was obtained from the ABARO variety by the mechanical extraction method. The GC-MS analysis of the biodiesel showed that methyl ricinoleate is produced by the acid and base transesterification method, yielding yields of 89 and 87 per cent biodiesel from HIRUY and ABARO oil, respectively. The GC-MS analysis of the biodiesel showed that methyl ricinoleate is the maximum composition of methyl ester of fatty acids. For biodiesel produced from oil of the HIRUY and ABARO seed varieties, the yields were 91.58% and 90.92%, respectively. The biodiesel produced from both varieties of castor seeds has a higher content of unsaturated fatty acid methyl esters. The findings of this study showed that the use of HIRUY castor seed oil may be preferable to ABARO castor seed oil for the production of biodiesel in terms of relatively higher oil and biodiesel yields, of acceptable oil quality and of high unsaturated fatty acid methyl ester content.

References

  1. Demirbas A. (2009)., Bio refineries current activities and future developments., Energy Conversion Managt, 50, 2782-2801.
  2. Venkata MS and Pandey A. (2013)., Biohydrogen production: An introduction in Biohydrogen., Pandey A, Chang JS, Hallenbeck PC, Larroche C, Eds.; Elsevier: Amsterdam, The Netherlands, 1-24.
  3. Osobajo OA, Otitoju A, Otitoju MA and Oke A. (2020)., The impact of energy consumption and economic growth on carbon dioxide emissions., Sustainability, 12: 7965.
  4. World Energy Outlook (2018)., Executive summary., International Energy Agency: France by DESK. Available at https://www.iea.org/weo2019/,
  5. Ministry of Water (2014)., Irrigation and Energy (MWIE): Biofuel development experience of Ethiopia.,
  6. Hilawe L and Yohannes S. (2008)., Rapid assessment of biofuels development status in Ethiopia., Proceedings of the national workshop on environmental impact assessment and biofuels.
  7. Afrol News (2021)., Ethiopia saves million from Sudanese oil imports., retrieved 28 January 2021 http:// www.afrol.com/articles/34821
  8. Yacob G. (2013)., Long-term bio-ethanol shift and transport fuel substitution in Ethiopia., Master of Science Thesis KTH School of Industrial Engineering and Management Energy Technology.
  9. UNCT Ethiopia (2008)., Biofuel a viable alternative source of energy?., Knowledge sharing forum UN Ethiopia.
  10. Demirbas A. (2008)., Comparison of trans-esterification methods for production of biodiesel from vegetable oils and fats., Energy Conversion Managt, 49, 125-130.
  11. Kurchania A. K. (2012)., Biomass Energy: The interface of biotechnology, chemistry & material science., Baskar C, Baskar S, Dhillon RS., 28, 468.
  12. Sharma M. P. (2009)., Biodiesel production from cottonseed and pongamia oil., J Indian Water Resources, 29, 49-58.
  13. Balat, M. and Balat, H. (2010)., Progress in biodiesel processing., Applied Energy, 87, 1815-1835.
  14. Onkar, S, Tyagi, B., Neeraj, K and Atray, AD. (2010)., Production, characterization and development of standards for biodiesel., Metrology society of India., MAPAN. 25, 197-218.
  15. Kar, T., Keles, S., Kaygusuz, K., (2016)., Biomass combustion, 22th International Energy and West view Special Studies in Natural Resources and Energy Management., Boulder, Colorado: West view Press. Environment Fair and Conference, 137-142.
  16. Chattopadhyay, S. and Sen, R. (2013)., Fuel properties, engine performance and environmental benefits of biodiesel produced by a green process., Applied Energy, 105, 319-326.
  17. Samir, N.A.K. (2014)., Biodiesel Production by Using Heterogeneous Catalyst., Chemical Engineering and Technology, Royal Institute of Technology Stockholm, 2014.
  18. Simonetta, Z. (2008)., Global perspective on production of biotechnology-based bioenergy and major trends., undefined
  19. Gebremeskel L and Tesfaye M. (2008)., A Preliminary assessment of socioeconomic and environmental issues pertaining to liquid biofuel development in Ethiopia., Heckett T, Aklilu N. Forum for Environment, Addis Ababa.
  20. Oladimeji, A. and Oyekunle, L.O. (2015)., Kinetics studies of biodiesel produced from castor oil via methylbutanolysis., Nigerian J. Chem Engineers, 64, 91-98.
  21. Center For Jatropha Promotion & Biodiesel (CJP) (2011)., A bean called castor can cut carbon & fuel in the future., (Accessed on 07 December 2019).
  22. Gui, MM, Lee, KT and Bhatia, S. (2008)., Feasibility of edible oil vs non-edible oil vs waste edible oil as biodiesel feedstock., Energy, 33, 1646-1653.
  23. Severino, L.S., Auld, D.L., Baldanz, M., Candido, M.J.D., Chen, G., Crosby, W., Tan, D., He, X., Lakshmamma, P., Lavanya, C., Machado, O.L.T., Mielke, T., Milan, M., Miller, T.D., Morris, J.B., Morse, S.A., Narvas, A.A., Soares, D.J., Sofiatt, V., Wang, M.L., Zanotto, M.D., Zieler, H.A. (2012)., Review on the challenges for increased production of castor., Agron J., 104, 853-880.
  24. Okechukwu, R.I., Wuchukwu, A.C. and Anuforo H.U. (2015)., Production and characterization of biodiesel from Ricinus communis seeds., Res J. Chem Sci., 5, 1-3.
  25. Ramezani, K., Rowshanzamir, S. and Eikani, M.H. (2010)., Castor Oil Transesterification reaction: A kinetic study and optimization of parameters., Energy, 35, 4142-4148.
  26. Getinet, A., Girma, T. and Eyasu, A. (2013)., A unique purple castor (Ricinus communis L,) variety: Hiruy., Ethiopian J Agric Sci., 3, 24, 163-164.
  27. Ministry of Agriculture and Natural Resources (MOANR) (2016)., Plant variety release, protection and seed quality control directorate crop variety register., 19, 172-173.
  28. Getinet A, Abel M and Dejene A. (2013)., Effect of plant and row spacing on the yield and oil contents of Castor (Ricinus communis L.) in the Central Rift Valley, Ethiopia Melkassa Agriculture Research Center., J. Agric. Sci, 24, 155-162.
  29. Getinet, A., Beemnet, M., Daniel, B. and Zewdnesh, D. (2011)., Registration of Castor (Ricinus communis L.) Variety Abaro Ethiop., J. Agri Sci, 21.
  30. Megueni, C., Tchuenteu, T.L., Noubissie, E., Derogoh, W.N. and Njintang Y.N. (2016)., Physico-Chemical properties of cake and oil from three castor bean accessions (Ricinus communis L.) grown in the field in two agroecological zones of Northern Cameroon., Int J Res. Studies Biosci., 4, 6-15.
  31. Akpan, U.G., Jimoh, A. and Mohammed, AD. (2006)., Extraction, characterization and modification of castor seed oil., Leonardo J Sci., 8, 43-52.
  32. Chika, M., Muhammad, M., Muhammad SJ, Musa UD and Aliyu S.B. (2019)., Assessment of low temperature refining process of castor seed oil for biodiesel production., American J Chem Biochem Engineer, 3, 1-6.
  33. Molla, A. and Nigus, G. (2014)., Synthesis and characterization of biodiesel from castor bean as alternative fuel for diesel engine., Am J Energy Engineering, 2, 1-15.
  34. Nakarmi, A. and Joshi, S. (2014)., A study on castor oil and its conversion into biodiesel by trans-esterification method., Nepal J Sci Technol., 15, 45-52.
  35. Abdelaziz, AI, Elamin, IH, Gasmelseed, GA. and Abdalla, BK. (2014)., Extraction, refining and characterization of Sudanese castor seed oil., J. Chem Engineer, 2, 2166-4366.
  36. Mata, TM, Martins, AA., Sikdar, S.K. and Costa, CA. (2011)., Sustainability considerations of biodiesel based on supply chain analysis., Clean Technol. Environ. Policy, 13, 655-671.
  37. Aldo, O, Temu, AK, Ogwok, P, and Ntalikwa, JW. (2012)., Physico-chemical properties of biodiesel from Jatropha and Castor Oils., Int J Renewable Energy Res., 2, 1.
  38. Wael, O. K. and Abdalrahim, M. B. (2016)., Physico-chemical characteristics of castor oil (Ricinus communis L.)., Sudan University of Science and Technology College of Agricultural Studies Department of Food Science and Technology.
  39. Habiba, D.M., Dahiru, D.M. and Babagana, G. (2017)., Extraction and characterization of castor seed oil., Int J Sci Engineering Res., 8, 2229-5518.
  40. Orijajogun, J.O. and Ayegba, C.O. (2017)., Physicochemical properties and fatty acid composition of Castor bean (Ricinus communis L.) seed oil., European J Biophysics, 5, 62-65.
  41. Beruk, A.B., Abel, W.O., Assefa, A.T. and Sintayehu, S.H., (2018)., Studies on Ethiopian Castor Seed (Ricinu Communis L.): Extraction and characterization of seed oil., J Nat Products Res., 4, 188-190.
  42. Dagde, KK. (2019)., Extraction of vegetable oil from avocado seeds for production of biodiesel., J. Appl. Sci. Environ. Manage, 23, 215-221.
  43. Kaniz, F, Anjan, D., Jannatul, F., Rakib, U., Maksudur, RK, Islam, MA. (2013)., Preparation of biodiesel from higher FFA containing castor oil., Int J Sci Engineering Res., 4, 12.
  44. Tarique, P., Sarfaraz, A.M., Aftab, A.K., Syed, T.H.S., Abdul, H.K., Zahid, H.L. and Jamil-Ur-Rehman, M. (2019)., Physicochemical composition and FTIR characterization of castor seed oil., Ukrainian Food J., 8, 4.
  45. Jialin, D., Can, G., Xingli, P., Haiyan, Z. and Xu, X., (2019)., Analysis of triacylglycerols in castor oil through liquid Chromatography-Mass spectrometry based on Fourier Transform–Ion Cyclotron Resonance-Mass Spectrometry and Gas Chromatography–Mass Spectrometry., J Chrom Sci., 57, 108-115.
  46. SAS Institute (2003)., SAS/STATA Guide for personal computer version 9.1., SAS Institute Inc, North Carolina. USA., 250-278.
  47. Wang, ML., Morris, JB., Pinnow, DL., Davis, J, Raymer, P, and Pederson, G.A. (2010)., A survey of the castor oil content, seed weight and seed-coat colour on the united states department of agriculture germplasm collection., Plant Genetic Resource: Characterization and Utilization.
  48. Chen, H. (2007)., Biodiesel production by the trans-esterification of cottonseed oil by solid acid catalysts., J Am Oil Chem Soc, 1, 11-15.
  49. Fore, SR., Porter, P. and Lazarus, W. (2011)., Net energy balance of small-scale on-farm biodiesel production from canola and soybean., Biomass Bioenergy, 35, 2234-2244.
  50. Dutta R, Sarkar, U and Mukherjee, A. (2015)., Soxhlet extraction of Crotalaria juncea oil using cylindrical and annular packed beds., Int J Chem Engineer Applications., 6, 130-133.
  51. Destaw, M., Getinet, A., Yohannes, P., Shiferaw, A. (2015)., Phenotypic variability and association of traits among yield and yield-related traits in Castor (Ricinus communis L.) Accessions at Melkassa, Central Rift Valley of Ethiopia., African J Agri Res., 12, 3562-3568.
  52. Patel, JR., Saiyed, MP, Patel, CG, Bhatt, RK., Bhatt, JP., 2010, Genetic variability and correlation studies in Castor (Ricinus Communis L.). Int J Agric Sci. 2010; 6:129-131., undefined, undefined
  53. Raheem, WA, Lawal, BA, Akanbi, WB. and Ojo, AM. (2019)., Assessment of seed oil yield and characteristics of ten Castor plant (Ricinus Communis L.) accessions in Ogbomoso, Nigeria., J Cereals Oil Seeds, 10, 23-28.
  54. Yusuf, AK, Mamza, PA, Ahmed, A.S. and Agunwa, U. (2015)., Extraction and characterization of castor seed oil from wild Ricinus communis Linn., Int J Sci, Environ Technol., 4, 1392-1404.
  55. Imasuen, A, Inegbedion, F, Erhabor, C, Osuide, M. (2014)., Isolation and characterization of castor seed oil and its utilization potential in the production of polyurethane foam., Walailak J Sci Technol., 11, 421-427.
  56. DEAS 847- 4 (2015)., Draft East African standard oils for cosmetic industry-methods: determination of acid value and free fatty acids, East African Community.,
  57. Oluwole, F.A, Abdulrahim, AT., Aviara, NA. and Umar, B. (2016)., Biodiesel yield from different varieties of castor seeds oil., Int J Phytofuels Allied Sci, 3, 130-137.
  58. Lemma, DB, Abagisa, MA and Kebede, AB. (2020)., Production of biodiesel from mixed Castor seed and Microalgal Oils: Characterization and optimization studies., https://assets.researchsquare.com/files/rs-66053/ v1stamped. pdf, (Retrieved at February 2020).
  59. Khaliq, IH, Naeem, B, Abbas, Q and Khalid, S. (2017)., Chemical composition and oil characterization of some accessions of Ricinus communis seeds., J Business Financial Affairs., 6, 2167-0234.
  60. Omari, A, Mubofu, EB and Mgani, QA. (2015)., Fatty acid profile and physico-chemical parameters of castor oils in Tanzania., Green Sustainable Chem., 5, 154-163.