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Effect of Temperature on the interaction of Alkali metal ions and 18-crown-6 ether in Binary system

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Author Affiliations

  • 1Department of Chemistry Ranilaxmibai Mahavidyalay, Parola, Dist Jalgaon 425111, MS, India
  • 2Department of Chemistry Ranilaxmibai Mahavidyalay, Parola, Dist Jalgaon 425111, MS, India
  • 3Department of Chemistry Ranilaxmibai Mahavidyalay, Parola, Dist Jalgaon 425111, MS, India

Res.J.chem.sci., Volume 15, Issue (4), Pages 35-41, October,18 (2025)

Abstract

18-crown-6 ether is widely accepted for their selectivity complexation and interaction with higher alkali metal ion, even their binding and complexation efficiency is strongly influenced by the temperature. In this research work, we investigate the effect of Variation of temperature on the stability of the complex and interaction between 18-crown-6 and alkali metals (Rb+ & Cs+) in a binary liquid systems. Viscosity and density measurements were employed to determine molecular interaction and thermodynamic parameters like ∆H

References

  1. Kikuchi Y., & Sakamoto Y. (2000)., Complex formation of alkali metal ions with 18-crown-6 and its derivatives in 1, 2-dichloroethane., Analytica chimica acta, 403(1-2), 325-332.
  2. Pedersen, C. J. (1988)., The discovery of crown ethers.3 Science, 241(4865), 536-540., undefined
  3. Izatt, R. M., Bradshaw, J. S., Nielsen, S. A., Lamb, J. D., Christensen, J. J., & Sen, D. (1985)., Thermodynamic and kinetic data for cation-macrocycle interaction., Chemical Reviews, 85(4), 271-339.
  4. Ohtsu, K., & Ozutsumi, K. (2003)., Thermodynamics of solvation of 18-crown-6 and its alkali-metal complexes in various solvents., Journal of inclusion phenomena and macrocyclic chemistry, 45(3), 217-224.
  5. Ozutsumi, K., Ohtsu, K., & Kawashima, T. (1994)., Thermodynamics of complexation of 18-crown-6 with sodium, potassium, rubidium, caesium and ammonium ions in N, N-dimethylformamide., Journal of the Chemical Society, Faraday Transactions, 90(1), 127-131.
  6. Czech, B. P., Babb, D. A., Son, B., & Bartsch, R. A. (1984)., Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds: synthesis and lithium ion complexation., The Journal of Organic Chemistry, 49(25), 4805-4810.
  7. El-Nemma, E. M., & Salman, S. R. (2004)., Molecular complexes of crown ethers: Part 8. Effect of surfactant on the charge transfer complexes of 18C6 with picric acid in the presence of alkali metal ions., Journal of inclusion phenomena and macrocyclic chemistry, 49(3), 267-273.
  8. Gokel, G. W., & Korzeniowski, S. H. (1982)., Crown Esters and Macrocyclic Polyether Lactones. In Macrocyclic Polyether Syntheses (220-266)., Berlin, Heidelberg: Springer Berlin Heidelberg.
  9. Salman, S. R., Derwish, G. A., & Al-Marsoumi, S. M. (1995)., Molecular complexes of crown ethers. Part 3. Effect of cations on charge transfer complexes with TCNE., Journal of inclusion phenomena and molecular recognition in chemistry, 23(3), 175-179.
  10. Amini, M. K., & Shamsipur, M. (1992)., Complex formation of hydronium ion with several crown ethers in 1, 2-dichloroethane, acetonitrile, and nitrobenzene solutions., Journal of solution chemistry, 21(3), 275-288.
  11. El-Nemma, E. M., & Salman, S. R. (2004)., Molecular complexes of crown ethers: Part 8. Effect of surfactant on the charge transfer complexes of 18C6 with picric acid in the presence of alkali metal ions., Journal of inclusion phenomena and macrocyclic chemistry, 49(3), 267-273.
  12. Feller, D. (1997)., Ab initio study of M+: 18-crown-6 microsolvation., The Journal of Physical Chemistry A, 101(14), 2723-2731.
  13. Semnani, A., & Shamsipur, M. (1991)., A competitive polarographic study of alkaline earth complexes with some crown ethers using the Tl (I)/Tl (Hg) couple as an electrochemical probe., Journal of electroanalytical chemistry and interfacial electrochemistry, 315(1-2), 95-101.
  14. Foster, R. (1980)., Electron donor-acceptor complexes., The Journal of Physical Chemistry, 84(17), 2135-2141.
  15. Bakshi, M. S., Kohli, P., & Kaur, G. (1998)., Micelle Formation by Anionic and Cationic Surfactants in 18-Crown-6Ether+. BETA. -Cyclodextrin+ Water Systems., Bulletin of the Chemical Society of Japan, 71(7), 1539-1542.
  16. Feller, D. (1997)., Ab initio study of M+: 18-crown-6 microsolvation., The Journal of Physical Chemistry A, 101(14), 2723-2731.
  17. Shannon, R. D. (1976)., Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides., Foundations of Crystallography, 32(5), 751-767.
  18. Hawrylak, B., Burke, S. E., & Palepu, R. (2000)., Partial molar and excess volumes and adiabatic compressibilities of binary mixtures of ethanolamines with water., Journal of solution chemistry, 29(6), 575-594.
  19. Kannappan, A. N., Vanaja, S., Palanivelu, N., & Rajendran, V. (1994)., Thermodynamic studies on binary liquid mixtures from ultrasonic data., Indian Journal of Chemical Technology, 1, 124-124.
  20. Kapadi, U. R., Hundiwale, D. G. & Patil, N. B. (2003)., Thermodynamic interaction of 2, 3-butanediol with water., Fluid phase equilibria, 208(1-2), 91-98.
  21. Hage, D. S., & Carr, J. D. (2011)., Analytical chemistry and quantitative analysis., (Vol. 30). Boston: Prentice Hall.
  22. Reddy, V. K., Rambabu, K., Devarajulu, T., & Krishnaiah, A. (1995)., Volume of mixing, speed of sound, and viscosity of methyl cellosolve with aliphatic alcohols at 308.15 K., Journal of Chemical and Engineering Data, 40(1), 124-127.
  23. Barrat, J. L., & Hansen, J. P. (2003)., Basic concepts for simple and complex liquids., Cambridge University Press.
  24. Kapadi, U. R., Hundiwale, D. G., Patil, N. B., & Lande, M. K. (2002)., Viscosities, excess molar volume of binary mixtures of ethanolamine with water at 303.15, 308.15, 313.15 and 318.15 K., Fluid phase equilibria, 201(2), 335-341.
  25. Borse, G. P. (2017)., Viscosities and densities for binary mi., Research Journal of Chemical, 7(1), 1-7.
  26. Aminabhavi, T. M., & Banerjee, K. (2001)., Thermodynamic interactions in binary mixtures of 1-chloronaphthalene with n-alkanes., Indian Journal of Chemistry Section A, 40(1), 53-64.
  27. Patra, K., Sadhu, B., Sengupta, A., Patil, C. B., Mishra, R. K., & Kaushik, C. P. (2021)., Achieving highly efficient and selective cesium extraction using 1, 3-di-octyloxycalix [4] arene-crown-6 in n-octanol based solvent system: experimental and DFT investigation., RSC advances, 11(35), 21323-21331.
  28. Ali, A., Nain, A. K., & Hyder, S. (1998)., Ion-solvent interaction of sodium iodide and lithium nitrate in N, N-dimethylformamide+ ethanol mixtures at various temperatures., Journal-Indian Chemical Society, 75, 501-505.
  29. Kapadi, U. R., Hundiwale, D. G., Patil, N. B., & Lande, M. K. (2003)., Effect of temperature on excess molar volumes and viscosities of binary mixtures of ethylenediamine and water., Fluid phase equilibria, 205(2), 267-274.
  30. Franjo, C., Jimenez, E., Iglesias, T. P., Legido, J. L., & Paz Andrade, M. I. (1995)., Viscosities and Densities of Hexane+ Butan-1-ol,+ Hexan-1-ol, and+ Octan-1-ol at 298.15 K., Journal of Chemical and Engineering Data, 40(1), 68-70.
  31. Wagner, B.D. (2021)., 2 Host–Guest Inclusion., Supramolecular Chemistry in Corrosion and Biofouling Protection, 17.