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A Heterogeneous approach to Sulfide Oxidation using TBHP-Functionalized Polystyrene Resin

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Author Affiliations

  • 1Department of Chemistry, PSGVPM’s SIP Arts, GBP Science and STKVS Commerce College, Shahada, 425409, MS, India
  • 2Department of Chemistry, PSGVPM’s SIP Arts, GBP Science and STKVS Commerce College, Shahada, 425409, MS, India
  • 3Department of Chemistry, PSGVPM’s SIP Arts, GBP Science and STKVS Commerce College, Shahada, 425409, MS, India

Res.J.chem.sci., Volume 15, Issue (4), Pages 24-28, October,18 (2025)

Abstract

Polymer supported reagent based synthetic strategies have been attracted the attention of chemists due to the providence of a heterogeneous reaction environment which eases the work up procedures and the recovered support can be reused. Owing to such advantages, the attempt has been made to develop heterogeneous oxidation method for sulfides under conventional and microwave conditions using resin bounded t-butyl hydroperoxide. The method succeeded to provide excellent yields in a short reaction time compared to conventional reports. The t-butyl hydroperoxide functionalized resin has been prepared and used as a heterogeneous reagent for the oxidation of sulfides. The recovered heterogeneous polymer support was reused for several times after re-functionalization using t-butyl hydroperoxide without loss in activity. The sulfoxides were prepared under the both conventional as well as microwave conditions from sulfides using supported oxidizing reagent.

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