Zr (IV) Complex derived from Salicylaldehyde and 2,4-dinitrophenylhydrazine Schiff base Ligand: Synthesis, Characterization and Biological Evaluation
Author Affiliations
- 1Department of Chemistry, V.S.S.D. College, Kanpur 208002 UP, India
- 2Department of Chemistry, V.S.S.D. College, Kanpur 208002 UP, India
- 3Department of Chemistry, V.S.S.D. College, Kanpur 208002 UP, India
Res.J.chem.sci., Volume 15, Issue (4), Pages 1-6, October,18 (2025)
Abstract
The Schiff base complex of Zirconium (IV) nitrateis synthesized with ligand obtained by condensation of Salicylaldehyde and 2,4-dinitrophenylhydrazine. The ligand and complex are characterized using Spectroscopic techniques, including FTIR, UV-Visible, 1HNMR and13CNMR. The biological activities of the metal-ligand complex have been investigated in relation to both gram-positive and gram-negative bacteria as well as various fungal species.
References
- Wang, X. Y., Avendaño, C., & Dunbar, K. R. (2011)., Molecular magnetic materials based on 4d and 5d transition metals., Chemical Society Reviews, 40(6), 3213-3238.
- Lekha, L., Raja, K. K., Rajagopal, G., & Easwaramoorthy, D. (2014)., Schiff base complexes of rare earth metal ions: Synthesis, characterization and catalytic activity for the oxidation of aniline and substituted anilines., Journal of organometallic chemistry, 753, 72-80.
- Sinn, E., & Harris, C. M. (1969). Schiff base metal complexes as ligands1. Coordination Chemistry Reviews, 4(4), 391-422., undefined, undefined
- Singh, P., Yadav, P., Sodhi, K. K., Tomer, A., & Mehta, S. B. (2024)., Advancement in the synthesis of metal complexes with special emphasis on Schiff base ligands and their important biological aspects., Results in Chemistry, 7, 101222.
- Gupta, K. C., & Sutar, A. K. (2008)., Catalytic activities of Schiff base transition metal complexes., Coordination Chemistry Reviews, 252(12-14), 1420-1450.
- Ghanghas, P., Choudhary, A., Kumar, D., & Poonia, K. (2021)., Coordination metal complexes with Schiff bases: Useful pharmacophores with comprehensive biological applications., Inorganic Chemistry Communications, 130, 108710.
- Chohan, Z. H., Arif, M., Akhtar, M. A., & Supuran, C. T. (2006). Metal‐based antibacterial and antifungal agents: synthesis, characterization, and in vitro biological evaluation of Co (II), Cu (II), Ni (II), and Zn (II) complexes with amino acid‐derived compounds. Bioinorganic Chemistry and Applications, 2006(1), 083131., undefined, undefined
- Süleymanoğlu, N., Demir, E. E., Direkel, Ş., & Ünver, Y. (2020)., Theoretical study and antimicrobial activities of New Schiff base derivatives with thiophene., Journal of Molecular Structure, 1218, 128522.
- Şabik, A. E., Karabörk, M., Ceyhan, G., Tümer, M., & Dığrak, M. (2012)., Polydentate schiff base ligands and their La (III) complexes: Synthesis, characterization, antibacterial, thermal, and electrochemical properties., International Journal of Inorganic Chemistry, 2012(1), 791219.
- Dalapati, S., Jana, S., Alam, M. A., & Guchhait, N. (2011). Multifunctional fluorescent probe selective for Cu (II) and Fe (III) with dual-mode of binding approach. Sensors and Actuators B: Chemical, 160(1), 1106-1111., undefined, undefined
- Basak, S., Sen, S., Banerjee, S., Mitra, S., Rosair, G., & Rodriguez, M. G. (2007)., Three new pseudohalide bridged dinuclear Zn (II) Schiff base complexes: Synthesis, crystal structures and fluorescence studies., Polyhedron, 26(17), 5104-5112.
- Naeimi, H., Safari, J., & Heidarnezhad, A. (2007)., Synthesis of Schiff base ligands derived from condensation of salicylaldehyde derivatives and synthetic diamine., Dyes and Pigments, 73(2), 251-253.
- Gaballa, A. S., Asker, M. S., Barakat, A. S., & Teleb, S. M. (2007)., Synthesis, characterization and biological activity of some platinum (II) complexes with Schiff bases derived from salicylaldehyde, 2-furaldehyde and phenylenediamine., Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 67(1), 114-121.
- Maity, D., Drew, M. G., Godsell, J. F., Roy, S., & Mukhopadhyay, G. (2010)., and characterization of Cu (II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime., Transition Metal Chemistry, 35(2), 197-204.
- Naeimi, H., & Moradian, M. (2010)., Synthesis and characterization of nitro-Schiff bases derived from 5-nitro-salicylaldehyde and various diamines and their complexes of Co (II)., Journal of Coordination Chemistry, 63(1), 156-162.
