International Science Community Association Research Journal of Recent Sciences 2277 - 2502 2 ISC-2012 2013 February 2 Study of Parametric Effects and Kinetic Modeling of Trans-sterification Reaction for Biodiesel Synthesis 67 75 EN Ahirwar J.R. 1 Department of Botany, Govt. College Niwari, District-Tikamgarh, M.P. INDIA Erhabor J.O. 1 Departement of Plant Biology and Biotechnology, University of Benin, P.M.B 1154, Benin City, NIGERIA Idu M. 2 Benson Idahosa University, PMB, 110, Benin City, NIGERIA Udo F.O. 3 Mehta Kavit 1 Mehsana Urban Institute of Sciences, Ganpat University, Ganpat Vidyanagar, Kherwa, Dist. Mehsana, North Gujarat, INDIA Patel B.N. 2 M.G. Science Institute, Navrangpura, Ahmadabad, INDIA Jain B.K. 3 Mishra Bishwambhar 1 Instrumental and Food Analysis Laboratory, School of Bio Sciences and Technology, VIT University, Vellore, Tamil Nadu, INDIA Suneetha Vuppu 2 Surekha M. 1 Toxicology Laboratory, Department of Botany, Kakatiya University, Warangal, Andhra Pradesh, INDIA Kiran S. 2 Naresh A. 3 Reddy S.M. 4 Krishania Suman 1 Department of Life Sciences,The IIS University, SFS Mansarovar, Jaipur -20 (Raj) INDIA Agarwal Kalpana 2 Kelkar TusharS. 1 Environmental Sciences Research Laboratory, Department of Botany, Wilson College, Mumbai, INDIA Bhalerao SatishA. 2 Naina Thangaraj 1 School of Biosciences and Technology, VIT University, Vellore, Tamil Nadu, INDIA Sharan Siddharth 2 Vuppu Suneetha 3 Javed Ahmad 1 Department of biochemical Engineering and Food Technology, Harcourt butler technological Institute, Kanpur, INDIA Khan Iffat 2 Department of Bioscience, Integral University Lucknow, INDIA Ashfaq Ahmad 3 kaushar Imam 4 Dubey S. 1 MVJ College of Engineering, Bangalore, Karnataka, INDIA. Kherwa V. 2 Department of Chemistry, C.D.L.University, Sirsa 125055, Haryana, INDIA. Kherwa V. 1 Department of Chemistry, C.D.L. University, Sirsa 125055, Haryana, INDIA Dubey S. 2 Department of Chemistry, MVJ College of Engineering, Bangalore, Karnataka, INDIA PatelKetan B. 1 Government Science College, Department of Chemistry, Gandhinagar, Gujarat, INDIA Patel YogeshM. 2 Patel RakshaB. 3 Udaykumar P. 1 Department of Chemistry, Birla Institute of Technology and Science, Pilani – K.K. Birla Goa Campus, Zuarinagar, Goa, INDIA Khanna T. 2 Behera R.N. 3 Hassan S.Z. 1 Department of Chemical Engineering, Indian Institute of Technology Bombay, Mumbai, INDIA Chopade S.A. 2 Vinjamur M. 3 > Research Paper 2012 11 21 2013 February 2 A kinetic study of KOH-catalyzed trans-esterification of sunflower oil with methanol is carried out. Overall trans-esterification reaction consists of three consecutive second-order reversible reaction steps. Effects of methanol-to-oil molar ratio (MR), reaction temperature and catalyst loading on fatty acid methyl esters (FAME), triglycerides (TG), diglycerides (DG) and monoglycerides (MG) are evaluated by using statistical approach of Taguchi method with L9 orthogonal array and analysis of variance (ANOVA). Orders of parametric effects on FAME, TG, DG and MG based on the relative contribution of the three parameters are presented. Catalyst loading is found to be a significant control parameter for FAME, TG and DG wherein insignificant parameter for MG. The temperature is insignificant for TG and DG reduction wherein it has an important influence on the minimization of MG. The combination of parameters which yielded ~95% of FAME with reasonable purity is 0.5 wt% catalyst loading, 50°C temperature and 7 MR. Copyright@ International Science Community Association