International Science Community Association Research Journal of Chemical Sciences 2231 - 606X 5 10 2015 October 18 New Ferromagnetically Coupled Dicopper (II) Complexes with s – bonding bridge 43 50 EN Shinde V.G. 1 * Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431004, MH, INDIA Ingale V.D. 2 RajbhojA.S. 3 Gaikwad S.T. 4 Runde M. 1 Department of Chemistry, Modibbo Adama University of Technology Yola Adamawa State, NIGERIA KubmarawaD. 2 Maina H.M. 3 Diedhiou Djibril 1 Laboratoire de Chimie Agro-Industrielle (LCA), ENSIACET, INP Toulouse, 4 Allée Emile Monso - BP 44362 - 31030 Toulouse Cedex 4, FRANCE Laboratoire d’Electrochimie et des Procédés Membranaires (LEPM), Université Cheikh Anta Diop de Dakar, BP 5085 Dakar-fann, SENEGAL DiattaMamadou Lamine 2 Faye Mamadou 3 Vilarem Gerard 4 SockOumar 5 Rigal Luc 6 ShamsaAl Sadi 1 Caledonian Centre for Creativity and Innovation, Caledonian College of Engineering, OMAN Mechanical and Industrial Engineering Department, Caledonian College of Engineering, OMAN Geetha Devi.M 2 MurtuzaAli Syed 3 Feroz.S 4 Varghese. M.J. 5 Ansari Anjum 1 1*Applied Chemistry Department, UIT, BU, Bhopal- 462026, INDIA Mechanical Engineering Department, UIT, BU, Bhopal- 462026, INDIA RajvaidyaRohit 2 Amlathe Sulbha 3 Vaidya Rohit 1 3 Department of Chemical Engineering, BITS Pilani Dubai Campus, P.O. Box 345055, Academic City, Dubai, UAE Department of General Sciences, BITS Pilani Dubai Campus, P.O. Box 345055, Academic City, Dubai, UAE Department of Mechanical Engineering, BITS Pilani Dubai Campus, P.O. Box 345055, Academic City, Dubai, UAE KarthiyayiniS. 2 Millerjothi N.K. 3 RanBahadur Yadav 1 Applied Chemistry Department, Faculty of Technology and Engineering, Kalabhavan, The Maharaja Sayajirao University of Baroda, Vadodara- 390001, INDIA > Research Paper 2015 10 1 2015 October 18 Four ternary binuclear complexes, [Cu(A),pichx](ClO (1 and 2) and [Cu(A)pichx](3 and 4) have been synthesized. In the complexes two metal centers are held together by - bonding bridge i.e. pichx= N,N’-bis(2-pyridylcarbonyl)-1,6-diaminohexane and A2 is 2,2’-bipyridyl or 1,10-phenanthroline or 2-hydroxybenzoic acid or 5-bromo-2-hydroxybenzoic acid coordinated to the metal ions as non-bridging ligands. The complexes were characterized by elemental analyses, conductance, magnetic susceptibility measurement, IR and electronic spectroscopy. The ESI-mass of the complex is consistent with the binuclear formulation. The complexes are observed to undergo a weak to moderate ferromagnetic coupling between two copper (II) ions. Copyright@ International Science Community Association