International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Synthetic, Characterization and Pesticidal Studies of Dibutyltin (IV)Derivatives of diphenylamine-2-amino-2’-Carboxylic acid

Author Affiliations

  • 1Department of Applied Sciences (Chemistry), Hindustan Institute of Technology and Management, Keetham, Agra, INDIA

Res.J.chem.sci., Volume 5, Issue (1), Pages 88-90, January,18 (2015)


Organotin (IV) derivatives of diphenylamines have synthesized by the reaction of dibutyltin diisopropoxide withdiphenylamine-2-amino-2’-carboxylic acid (dpac) in 1:1, 1:2 and 2:1 molar ratios. These derivatives are characterized byelemental analyses, IR spectral analyses, PMR spectral analyses and molar conductance measurements. The products arescreened for pesticidal activities against the pest ‘Red Flour Beetle’ (Tribolium castaneum). The derivatives so formedexhibited enhanced pesticidal activities compared to the ligand.


  1. Arakawa Y., Main Group Metal Chem., 12, 1 (1989)
  2. Saxena A.K., Appl. Organometal. Chem., 1, 39 (1987)
  3. Dey K. and Mukhopadhyay S., J. Indian Chem. Soc., 78, 73 (2001)
  4. Gupta P.R., Mishra R.C. and Dogra G.S., Indian J. Agric. Sci., 51, 514 (1981)
  5. Mittal P., Pachouri M.K. and Sharma R.C., Studies on monobutyltin (IV) derivatives of 3-hydroxy-2-naphthoic acid, Asian J. of Chemistry, 18(1), 737-739 (2006)
  6. Mittal P., Pachouri M.K. and Sharma R.C., Pesticidal behavior of monobutyltin (IV) derivatives of salicylic acid against Red Flour Beetle, J. Ind. Council Chem., 23(2), 23-26 (2006)
  7. Mittal P. and Pachouri M. K., Characterization and Pesticidal studies of some new Dibutyltin (IV) derivatives of 1-hydroxy-2-naphthoic acid, Res. J. Chem. Sci., 2(4), 61-63 (2012)
  8. Mittal P., Pachouri M. K. and Singh N. P., Synthetic, Characterization and Pesticidal studies of Dibutyltin (IV) derivatives of salicylic acid, Res. J. Chem. Sci., 3(3), 79- 81 (2013)
  9. Pachouri M.K. and Mittal P., Characterization and Pesticidal studies of Dibutyltin (IV) derivatives of diphenylamine-2-hydroxy-2’-carboxylic acid, Res. J. Chem. Sci., 4(1), 75-77 (2014)
  10. Gaur D.P., Srivastava G. and Mehrotra R.C., J. Organometal. Chem., 63, 221 (1973)
  11. Vogel A.I., Quantitative Inorganic Analysis, Longmans, London, (1975)
  12. Kettle S.F.A., Coordination Compounds, Thomas Nelson and Sons, 168 (1975)
  13. Bellamy L.J., The Infra-red Spectra of Complex Molecules, Methuen, London, (1962)
  14. Nakanishi K. and Soloman P.H., Infra-red Absorption Spectroscopy 2nd Ed., Holden-Day, London, (1962)
  15. Silverstein R.M., Bassler G.C. and Morrill T.C., Spectrometric Identification of Organic Compounds, John Wiley, New York, (1981)
  16. Brown M.P., Okawara R. and Rochow E.G., Spectrochim. Acta, 16, 595 (1960)
  17. Pardhy S.A., Gopinathan S. and Gopinathan C., Synth. React. Inorg. Met. Org. Chem., 13, 305 (1983)
  18. Peruzzo V., Plazzogna G. and Tagliavini G., Organometal. Chem., 24, 347 (1970)
  19. Srivastava, T.N. and Singh, J.D., Indian J. Chem., 24A, 489 (1985)
  20. Asahi Research Centre Co. Ltd. Tokyo, Hand Book of Proton NMR Spectra and Data, Vol. 2nd & 4th, Academic Press, Japan, (1985)
  21. U.S. Environmental Protection Agency, Report of DDT Advisory Committee (1975)