International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Kinetic and Mechanistic Investigation of the Oxidation of Indole Using Peroxomonosulphate in Acetone Medium

Author Affiliations

  • 1Research and Development Centre, Bharathiar University, Coimbatore 641046, Tamil Nadu, INDIA
  • 2 Dept of Chemistry, A.V.V.M.S.P College, Poondi, 613503, Tamil Nadu, INDIA
  • 3 MAM College of engineering, Siruganur, Trichy-621105, Tamil Nadu, INDIA
  • 4 Dept of Chemistry, SVVCAS, Dharmapuri Tamil Nadu, INDIA

Res.J.chem.sci., Volume 4, Issue (8), Pages 7-11, August,18 (2014)

Abstract

The kinetic study of oxidation of indole using peroxomonosulphate was carried out in aqueous acetone medium in the temperature variation of 293-308 K. The influence of [indole], [peroxomonosulphate], [H+], ionic strength, percentage of acetone and temperature on the rate of reaction was carried out. The order with respect to [peroxomonosulphate] and [indole] was also one. The total reaction was second order, first order each with respect to [Indole] and [PMS]. No effect of [H+] on the rate was observed while increase of [H+]. Variations of ionic strength had no effect and Increase of percentage of aqueous acetone decreased the rate. Suitable mechanism in conformity with the kinetic observations has been proposed and Activation and thermodynamic parameters have been computed basis of the observed data. The product isatin was confirmed from the IR and NMR spectral analysis.

References

  1. Ermer O. and Robke C., Helv. Chim. Acta, 86, 2908 (2003)
  2. Spiro M., Electrochim. Acta24, 313 (1979)
  3. Ball D.L. and Edwards J.O., J. Am. Chem. Soc.,78, 1125 (1956)
  4. Kolthoff I.M., and Miller I.K., J. Am. Chem. Soc., 73, 3055 (1951)
  5. Madhavan J., Maruthamuthu P., Murugesan S. and Ashok Kumar M., Appl. Catal., A General,368, 35 (2009)
  6. Murugavelu M., Andal P., Shailaja S. and Ramachandran M.S., J. Mol. Catal. A: Chem306,1 (2009)
  7. Mehrotra M. and Mehrotra R.N., Polyhedron27, 2151 (2008)
  8. Lente G. and Fabian J., J. Chem. Soc. Daltan Trans,38,4268 (2007)
  9. Dubey S., Hemkar S., Khandelwal C.L. and Sharma P.D.,Inorg. Chem. Commu,5, 903 (2002)
  10. Balakrishnan T. and Damodarkumar S., J. Appl. Polymer Science,76, 1564 (2000)
  11. Rani S.K., Easwaramoorthy D., Bilal I.M. and Palanichamy M., Appl. Catal., A General369, 1 (2009)
  12. Khalid M.A. A. Arabian J., Sciences and Engin, 33, 199 (2008)
  13. Edwards J.O., Ed. Peroxide Reaction Mechanisms;Interscience: New York, 67-106 (1962)
  14. Stephen J., J. Korean Chem. Soc.,57(2), 210215 (2013)
  15. Chandramohan G., Kalyanasundharam S. and Renganathan R., Int J Chem Kinet,34, 569 (2002)
  16. Montgomery R.E., J. Am. Chem. Soc.96, 7820 (1979)
  17. Laidler K.J., Chemical Kinetics, Tata-McGraw Hill: New Delhi, 229 (1965)