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Study on novel polymeric ligand based on bismaleimide

Author Affiliations

  • 1Chemistry Department, Sir P.T. Science College, Modasa, Gujarat, India
  • 2Chemistry Department, Sir P.T. Science College, Modasa, Gujarat, India

Res.J.chem.sci., Volume 12, Issue (2), Pages 41-45, June,18 (2022)


Michael addition reactions of 1, 4-phenylene bismaleimide (PB) with benzidine dicarboxylic acid (BDC) affords polymeric ligand (PB-BDC). Elemental analysis, spectral study and TGA were carried out of all PB-BDC. The transition metal chelates of Cu2+, Ni2+, Zn2+, Co2+, Mn2+ metal ions with PB-BDC were prepared and characterized all by metal: ligand ratio, spectral studies, magnetic moment and thermogravimetry. Antimicrobial activity of all polymer samples was carried out against various plant pathogens.


  1. Gu, A. (2006)., High performance bismaleimide/cyanate ester hybrid polymer networks with excellent dielectric properties., Composites Science and Technology, 66(11-12), 1749-1755.
  2. Chuang, K. C., Bowman, C. L., Tsotsis, T. K., & Arendt, C. P. (2003)., 6F-polyimides with phenylethynyl endcap for 315-370 C applications., High performance polymers, 15(4), 459-472.
  3. M. J., Voytekunas, V. Y., & Rusanov, A. L. (2006)., State of the Art Organic Matrices for Highperformance Composites: A Review., Iranian Polymer Journal, 15, 65 (2006).
  4. Mangalgiri, P. D. (2005). Polymer-matrix composites for high-temperature applications. Defence Science Journal, 55(2), 175., undefined, undefined
  5. Varma, I. K., & Varma, D. S. (1984)., Addition polyimides. III. Thermal behavior of bismaleimides., Journal of Polymer Science: Polymer Chemistry Edition, 22(6), 1419-1433.
  6. Pascal, T., Mercier, R., & Sillion, B. (1989)., New semi-interpenetrating polymeric networks from linear polyimides and thermosetting bismaleimides. 1: Synthesis and characterization of starting components., Polymer, 30(4), 739-744.
  7. Qin, H., Mather, P. T., Baek, J. B., & Tan, L. S. (2006)., Modification of bisphenol-A based bismaleimide resin (BPA-BMI) with an allyl-terminated hyperbranched polyimide (AT-PAEKI)., Polymer, 47(8), 2813-2821.
  8. Harris, F. W., Wilson, D., Stenzenberger, H. D., & Hergenrother, P. M. (1990)., Polyimides., D. Wilson, HD Stenzenberger, PM Hergenrother, Chapman and Hall edt., New York, 23-96.
  9. Pan, J. P., Shiau, G. Y., Lin, S. S., & Chen, K. M. (1992)., Effect of barbituric acid on the self‐polymerization reaction of bismaleimides., Journal of applied polymer science, 45(1), 103-109.
  10. Yu, F. E., Hsu, J. M., Pan, J. P., Wang, T. H., & Chern, C. S. (2013)., Kinetics of Michael addition polymerizations of n, n′‐bismaleimide‐4, 4′‐diphenylmethane with barbituric acid., Polymer Engineering & Science, 53(1), 204-211.
  11. Varma I. K. and Varma D. S. Varma (1987)., Polymer Chemistry Edition., Journal of Polymer Science:, 5, 568.
  12. D′ alelio, G. F., E. T. Hofman, and J. R. Zeman (1969)., Chelating Polymers. I. Monomeric Hydroxyaryl aminoacetic acids as prototype chelating compounds., Journal of Macromolecular Science—Chemistry 3.5, 959-989.
  13. R. L. Cook (2005)., U.S. Patent No. 6,933,046. Washington, DC: U.S. Patent and Trademark Office., undefined
  14. Crivello, J. V., & Lam, J. H. W. (1979). Photosensitive polymers containing diaryliodonium salt groups in the main chain., Journal of Polymer Science: Polymer Chemistry Edition, 17(12), 3845-3858., undefined
  15. A. I. Vogel (1978)., Textbook of Quantitative Chemical Analysis., ELBS 4th Edn. London. p. 317.
  16. W. R. Baily and E. G. Scott (1966)., Diagnostic Microbiology., The C. V. Moshy Co. St. Lovis, p. 257.
  17. Mehta, K. K., & Patel, A. D. (2016)., Synthesis, characterization, biological and chelating properties of new antipyrine derived azo dyes and its transition metal complexes., Acta Chimica and Pharmaceutica Indica, 6, 26-31.
  18. Patel, D. C. (1972)., Studies in some NI (II) and CU (II) Complexes., Journal of Indian Chemical Society, 49, 1041.
  19. D. Oza, K. N. Kaul and R. K. (1996). Mehta, Indian Journal of Chemistry, 7, 927., undefined, undefined
  20. Lewis, J. (1960)., R, G. Wilkins, Modern Coordination Chemistry., Inter science Publ. Co., New York. 290.
  21. Pappalardo, R. (1960)., Note on the optical absorption of MnCl2 and MnBr2., The Journal of Chemical Physics, 33(2), 613-614.