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Viscosity and Excess viscosity for non-polar system from 298.15 to 323.15K

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Author Affiliations

  • 1Department of Chemistry, Janta College Bakewar, Etawah, India
  • 2Department of Chemistry, Janta College Bakewar, Etawah, India
  • 3Department of Physics, Janta college Bakewar, Etawah, India

Res. J. Recent Sci., Volume 11, Issue (2), Pages 23-33, April,2 (2022)

Abstract

Viscosity and excess viscosity for a non-polar liquid mixture cyclohexane (1)+ 2,2,4-trimethylpentane (2) were computed at temperature 298.15,303.15,308.15,313.15,318.15,323.15K with mole fraction of cyclohexane. Calculated theoretical values compared and tested with the measured data of Jose M. Navaza. Prigogine-Flory-Patterson (PFP), Glinski (GLI) and Ramaswamy (RS) model based on non-associated and associated process respectively. Nature and the behaviour of binary system was studied with help of these models. Redlich- Kister relation was utilized to determine the respective parameters and deviation from experimental values in term of standard deviation (δɳ). Extent of interactions between the like and unlike components and nature of binary system can be predicted by excess viscosity. Estimation of experimental findings were carried out with help of Jouyban Acree Model, McAllister model. Jouyban Acree Model correlate the experimental findings more accurately than McAllister model.

References

  1. Chen, Y. S., Lin, C. C., & Liu, H. S. (2005)., Mass transfer in a rotating packed bed with viscous Newtonian and non-Newtonian fluids., Industrial & engineering chemistry research, 44(4), 1043-1051. doi:10.1021/ie049 9409
  2. Tangsathitkulchai C. (2004)., Effect of Medium Viscosity on Breakage Coefficients of Quartz in a Laboratory Ball-Mill., Ind Eng Chem Res., 43(9), 2104-2112. doi:10.1021/IE020516M
  3. Xia X., and Wolynes P.G. (2001)., Diffusion and the mesoscopic hydrodynamics of supercooled liquids., J Phys Chem B., 105(28), 6570-6573. doi:10.1021/JP004616M
  4. Srivastava N., Davenport R.D. and Burns, M.A. (2005)., Nanoliter viscometer for analyzing blood plasma and other liquid samples., Anal Chem. 77(2), 383-392. doi:10.1021/ AC0494681
  5. Behrends, R., and Kaatze U. (2000)., Structural isomerization and molecular motions of liquid n-aikanes. Ultrasonic and high-frequency shear viscosity relaxation., J Phys Chem A., 104(15), 3269-3275. doi:10.1021 /JP994015Z
  6. Kelly W.J., and Patel S. (2001)., Flow of viscous shear-thinning fluids behind cooling coil banks in large reactors., Ind Eng Chem Res., 40(17), 3829-3834. doi:10.1021/IE000918Z
  7. D’Arrigo, G., Briganti, G., and Maccarini M. (2006)., Shear and longitudinal viscosity of non-ionic C12E8 aqueous solutions., J Phys Chem B., 110(10), 4612-4620. doi:10.1021/JP056738Q
  8. Awasthi, N., Gangwar, V. S., Prakash, S. K. S. G., & Shukla, R. K. (2017)., Viscosity and Excess Viscosity for Associated Binary Systems at T=(298.15, 308.15 and 318.15)., International Journal of Thermodynamics, 20(4), 183-189.
  9. Gómez-Díaz, D., Mejuto, J. C., & Navaza, J. M. (2001)., Physicochemical properties of liquid mixtures. 1. Viscosity, density, surface tension and refractive index of cyclohexane+ 2, 2, 4-trimethylpentane binary liquid systems from 25oC to 50oC., Journal of Chemical & Engineering Data, 46(3), 720-724.
  10. Prigogine I. (1957)., Molecular theory of solutions., cited 2021 Jul 23; Available from: https://agris.fao.org/agris-search/search.do?recordID=US201300526922
  11. Abe, A. and Flory P.J. (1965)., The Thermodynamic Properties of Mixtures of Small, Nonpolar Molecules., J Am Chem Soc. 87(9), 1838-1846. doi:10.1021/JA 01087A003
  12. Flory P.J. (1965)., Statistical Thermodynamics of Liquid Mixtures., J Am Chem Soc., 87(9),1833-1838. doi:10.1021/JA01087A002
  13. Flory, P.J., Orwoll, R.A. and Vrij, A. (1964)., Statistical Thermodynamics of Chain Molecule Liquids. I. An Equation of State for Normal Paraffin Hydrocarbons., J Am Chem Soc., 86(17), 3507-3514. doi:10.1021/JA01071A023
  14. Patterson, D. and Rastogi, A.K. (1970)., The surface tension of polyatomic liquids and the principle of corresponding states., J Phys Chem., 74(5), 1067-1071. doi:10.1021/J100700A017
  15. Prigogine I. and Saraga L. (1952)., Test of monolayer model for surface tension of simple liquids., J. Chem.Phy., 49, 399-407.
  16. Ramaswamy K. and Anbananthan D. (1981)., Study of Molecular-Interactions with Acoustic-Impedance as A Parameter., Acoustica, 48(4), 281-282
  17. Gliński J. (2003)., Determination of the conditional association constants from the sound velocity data in binary liquid mixtures., J Chem Phys. 118(5), 2301-2307. doi:10.1063/1.1534579
  18. Redlich O. and Kister A.T. (1948)., Algebraic Representation of Thermodynamic Properties and the Classification of Solutions., Ind Eng Chem., 40(2), 345-348. doi:10.1021/ie50458a036
  19. McAllister RA. (1960)., The viscosity of liquid mixtures., AIChE J. 16(3), 427-431. doi:10.1002/aic.690060316
  20. Riddick J.A. and Bunger W.B. (1986)., Organic solvent technique of chemistry., 4th ed. NewYork:Willey.
  21. Macedo P.B. and Litovitz T.A. (1965)., On the relative roles of free volume and activation energy in the viscosity of liquids., The J of Chem Phys., 142(1), 245-256. doi:10.1063/1.1695683
  22. Natta, G. and Baccaredda, M.,(1948). Sulla velocita di prppagazione degli ultrasuoni nelle miscele ideali. Atti Accard Naz Lincei.4,360., undefined, undefined
  23. Shukla, R. K., Awasthi, N., Kumar, A., Shukla, A., & Pandey, V. K. (2011)., Prediction of associational behaviour of binary liquid mixtures from viscosity data at 298.15, 303.15, 308.15 and 313.15 K., Journal of Molecular Liquids, 158(2), 131-138.
  24. Verma, R., and Singh, K.P., (2019)., Evaluation of the Kirkwood Buff Coefficients for a high power tunable dye laser solution., AIP Conf Proc., Vol. 2136, No. 1, p. 040013). AIP Publishing LLC. doi:10.1063/1.5120927
  25. Pandey, J. D., Soni, N. K., Dey, R., & Verma, R. (2004)., Excess functions of binary liquid mixtures at varying pressures., Fluid phase equilibria, 215(1), 17-22.
  26. Shukla, R.K., Kumar, A., Srivastava,U., Srivastava, K., and Pandey, V.K. (2016)., Interpretation of Association Behavior and Molecular Interactions in Binary Mixtures from Thermoacoustics and Molecular Compression Data., Int J of Thermophys., 37(9), 1-18. 1007/S10765-016-2096-3
  27. Jouyban, A., Khoubnasabjafari, M., Vaez-Gharamaleki, Z., Fekari, Z., & Eugene Jr, W. (2005)., Calculation of the viscosity of binary liquids at various temperatures using Jouyban–Acree model., Chemical and Pharmaceutical Bulletin, 53(5), 519-523.
  28. Awasthi, N. (2021)., Estimation of Viscosity of Binary system at Various Temperatures by Jouyban Acree Model and McAllister Model., International research journal of modernization in engineering technology and science, 3(9), 865-871.