International E-publication: Publish Projects, Dissertation, Theses, Books, Souvenir, Conference Proceeding with ISBN.  International E-Bulletin: Information/News regarding: Academics and Research

Synthesis, Characterization and Antimicrobial activity of Cobalt (II) Complexes with Pyrimidine derivatives

Author Affiliations

  • 1GCRC, P.G. Department of Chemistry, Govt. Dungar College, Bikaner, Rajasthan MGS University, Bikaner, 334001, India
  • 2GCRC, P.G. Department of Chemistry, Govt. Dungar College, Bikaner, Rajasthan MGS University, Bikaner, 334001, India
  • 3Govt. Engineering College Bikaner, Rajasthan, India
  • 4GCRC, P.G. Department of Chemistry, Govt. Dungar College, Bikaner, Rajasthan MGS University, Bikaner, 334001, India

Res.J.chem.sci., Volume 6, Issue (3), Pages 48-55, March,18 (2016)

Abstract

In this paper synthesis, spectral and antibacterial studies of Cobalt (II) complexes with pyrimidine derivates have been reported. Elemental analysis, infrared, electronic spectra and magnetic susceptibility studies have been used for characterisation. Antimicrobial activities of these pyrimidine derivates and its complexes have also been described. These complexes show UV bands in region about 11376 cm-1 to 26315 cm-1 and tentative assignment 4T1g(F)&

References

  1. Pecoraro V.L., Baker M.J., Butler W.M. and Bonadies J.A., (1987)., Manganese Complexes of Relevance to Enzymes Containing Multinuclear Manganese Centers, Recueil Trav. Chim., 106, 221.
  2. Garg B.S, Bhojak N., Sharma R.K., Bist J.S. and Mittal S. (1999)., Separation and preconcentration of metal ions and their estimation in vitamin, steel and milk sample using o-vanillin-immobilized silica gel., Talanta, 48(1), 49-55.
  3. Bhojak N., Gudasaria D.D., Khiwani N. and Jain R. (2007)., Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn (II) With Amide Containing Ligands., E-Journal of Chemistry, 4(2), 232-237.
  4. Garg B.S., Bhojak N. and Nandan D. (2005)., Micellar spectrofluorimetric determination of lead (II) in natural water, waste water and egg samples with N-(2ʹ-pyridyl)- 2- hydroxybenzamide., Ind. J. Chem., 44A, 1504.
  5. Raja Ram, Verma K.K., Solanki K.and Bhojak N. (2015)., Microwave assisted synthesis, spectral and antibacterial investigations on complexes of Co (II) with amide containing ligands., International Journal of New Technologies in Science and Engineering. 2(6), 92-100.
  6. Verma K.K., Soni Gupta P., Solanki K.and Bhojak N. (2015)., Microwave Assisted Synthesis, Characterisation and Anti microbial activities of few Cobalt (II) Thiosemicarbazones Complexes., World Journal of pharmacy and pharmaceutical sciences., 4(11), 1673-1683.
  7. Raja Ram, Verma K.K., Bhandari H.S. and Bhojak N. (2015)., Microwave assisted synthesis, spectral and antibacterial investigations on complexes of Ni (II) with amide group containing ligands., IARJSET, 2(11), 40-43.
  8. Singh B. and Bhojak N. (2008)., Microwave assisted synthesis, spectral and antibacterial investigations on complexes of Mn (II) with amide containing ligands., RJC, 1(1), 105-109,
  9. David Pines S. and David Recknow A. (2002)., Effect of Dissolved Cobalt (II) on the ozonation of Oxalic Acid., Environ. Sci. Technol., 36(19), 4046-4051,
  10. Akira Kurata (1974)., Cobalt content in the shallow sea sediments., Journal of Oceanography, 30(4), 199-202.
  11. Sharma R.M., Panigraphi S. and Azeez P.A. (1987)., Effect of cobalt on the primary productivity of Spirulina platensis., Bulletin of Environmental Contamination and Toxicology, 39(4), 716.
  12. Bresson C., Esnouf S., Lamouroux C., Solari P.L. and Auwer Den X.A.S. (2006)., Investigation of biorelevant cobalt complexes in aqueous media., New J. Chem., 30, 416–424.
  13. Yan Y., Neville A. and Dowson D. (2007)., Tribo-corrosion properties of cobalt-based medical implant alloys in Simulated Biological Environments., Wear, 263, 1105.
  14. Yadav N. and Bhojak N. (2013)., Microwave assisted synthesis, spectral and antibacterial investigation on Co (II) complexes with amide ligands., The Int. J. Eng. Sci., 2(2), 166-168,
  15. Kabanos T.A. and Tsangaris J.M. (1984)., Deprotonated and non-deprotonated complexes of n- (2-aminophenyl) pyridine-2-carboxamide and n-(3-aminophenyl)pyridine-2- carboxamide with Co(II), Ni(II), Cu(II) and Pd (II)., J. Coord. Chem., 13(2), 89- 103.
  16. Nonoyama M. and Yamasaki K. (1973)., Cobalt (II) and copper (II) complexes of several potentially terdentate N-substituted picolinamides., Inorg. Chem. Acta., 7, 676-680.
  17. Barnes D.J., Champman R.L., Stephen F.S. and Vagg R.S. (1981)., Studies on the metal amide bond. II. Metal complexes of the flexible N4 ligand N, N-bis (2-pyridinecarboxamide) 1, 2-ethane., Inorg. Chem. Acta, 51, 155-162.
  18. Kokunov Y.V., Gorbunova Y.E., Kovalev V.V.and Kozyukhin S.A. (2013)., Russian Journal of Inorganic Chemistry, 58 (10), 1187-1192., undefined