Vibrational Spectroscopic Studies of Schiff base compounds derived from 4-Amino Antipyrine by Quantum chemical investigations
Author Affiliations
- 1Govt. Kamla Raja Girls Autonomous Post Graduate College, Gwalior, INDIA
- 2 Department of Chemistry, Government Autonomous Post Graduate College, Datia, INDIA
Res.J.chem.sci., Volume 5, Issue (9), Pages 49-59, September,18 (2015)
Abstract
In this study 4-N-[Salicyledene]amino antipyrine (SAAPy),Dimethylamino)benzalidene] amino antipyrine (BAAPy),4-N-[(þ- Dimethylamino)benzalidene] amino antipyrine (þ-DABAAPy) schiff base of 4-Amino Antipyrine has been subjected to experimental and theoretical study by using SemiThe normal mode frequencies of vibration were analyzed. The theoretically obtained results with the experimental data reported. A good correlation has been observed between experimental and calculated values of vibration modes.
References
- Fessenden R J and Fessenden J S, Spectrophotometric studies on some Schiff bases derived from benzidine, Organic Chemistry, 542-543 (1989)
- Abdullah Hussein kshash, FT-IR and UV/Vis Spectroscopic Study of Some Schiff bases Derived From amino Benzoic acid and Bromo benzaldehyde, Journal of chemistry, 2(1), 1-5 (2011)
- Desai S.B., Desai P.B. and Desai K.R., Synthesis and Spectroscopic Studies of New Schiff Bases, Heterocyclic Communications, 83-90 (2001)
- Mohanambal D and Arul Antony S., Synthesis, Characterization and Antimicrobial activity of some novel schiff Base 3d Transition Metal Complexes Derived from Dihydropyrimidinone and 4- Aminoantipyrine, Res. J. Chem. Sci., 4(7), 11-17 (2014)
- Nagajothi A., Kiruthika A., Chitra S. and Parameswari K., Fe(III) Complexes with Schiff base Ligands: Synthesis, Characterization, Antimicrobial Studies, Res. J. Chem. Sci., 3(2), 35-43 (2013)
- Singh Rajeev, Kumar D., Singh Bhoop, Singh V.K. and Sharma Ranjana, Molecular structure, vibrational spectroscopic and HOMO, LUMO studies of S-2-picolyl-N-(2-acetylpyrrole) dithiocarbazate Schiff base by Quantum Chemical investigations, Res. J. Chem. Sci., 3(2), 79-84 (2013)
- Kumar D., Agrawal M.C. and Rajeev Singh, Computational Study of Benzaldehyde Thiosemicarbazone, Mat. Sci. Res. Ind., 3(1A), 37 (2006)
- Hyper ChemTM Professional Release 8.0 for Window Molecular Modeling System, Dealer: Copyright ©, Hypercube, Inc (2002)
- Stewart J.J.P., Lipkowinz K.B., Boyal D.B., (Eds.); Reviews in Computational Chemistry, V.C.H., 1, 45 (1990)
- Bingham Richard C., Dewar M. J.S. and Lo D.H., Ground state of molecules. XXV. MINDO/3, Improved version of the MINDO Semi-empirical SCF-MO method, J. Am. Chem. Soc., 97(6), 1285 (1975)
- Arora K, Kumar D., Burman K , Agnihotri S and Singh B, Theoretical studies of 2-nitrobenzaldehyde and furan-2-carbaldehyde Schiff base of 2-amino pyridine, J. Saudi Chem. Soc., 15, 161 (2011)
- Singh R, Goswami Y.C., Goswami R, Semiempirical and Experimental Investigation on Coordination behavior of S-methyl – -N-(4-methoxyphenylmethyl) methylenedithiocarbazate Schiff base towards Co(II), Ni(II) and Cu(II) metal ions, Journal of Chemistry, 1 (2011)
- Kumar D., Agrawal M.C. and Rajeev Singh, Theoretical Investigation of IR and Geometry of the S-benzyl--N-(2-furylmethylketone)dithiocarbazate Schiff base by Semiempirical Methods, Asian J. Chem., 19(5), 3703 (2007)
- Kumar D., Agrawal M.C. and Rajeev Singh, Theoretical Study of Pyridine-2-Amidoxime by Semi-empirical Methods, Oriental J. Chem., 22(1), 67 (2006)