Synthesis and Characterization of Co+2, Ni+2, Cu+2, Zn+2 and Hg+2 Complexes with 1,1,2,2-tetrakis (Sodium Thioproponate)ethylene
Author Affiliations
- 1Teacher Oreparation Institute, Ministry of education, Nineveh, IRAQ
Res.J.chem.sci., Volume 3, Issue (7), Pages 9-14, July,18 (2013)
Abstract
The new ligand 1,1,2,2-tetrakis(sodium thioproponate) ethylene, has been prepared from the reaction of disodium salt of 3-mercaptoproponic acid and tetrachloroethylene in (4:1) molar ratio. Diand tetranuclear complexes were obtained by direct reaction of the above ligand with Co+2, Ni+2, Cu+2, Zn+2 and Hg+2 metal ion in (1:2) and (1:4) ligand to metal molar ratio. The prepared complexes were characterization by elemental analysis, spectral studies (FTIR.,UV/vis), magnetic measurements, conductivity measurements. Electronic spectra and magnetic moment values indicate the presence of tetrahedral geometric around the metal ions.
References
- Liang L.C., Metal complexes of chleating diarylamido phosphine ligands, Coord. Chem. Rev., 250, 1152-1177 (2006)
- Lin S. J., Ho Y.C., Gau, Synthesis, characterization and structure of group 4 metallocene complexes of some difunctional ligands containing oxygen and sulfur donors, J.Chin.Chem.Soc., 46, 539-544 (1999)
- Seleem H.S., Mostafa M., Stefan S.L. and Abdel-Aziz E., Structural Diversity of 3d Complexes of an Isatinic Quinolyl Hydrazone, Res.J.Chem.Sci., 1(5), 67-72 (2011)
- Sinfelt J.H., Bimetallic Catalysis, Wiely,New York, (1983)
- Yousif E., Farina Y., Grasia A., Salih N. and Salimon J., Structure and Fangicidal activity of some diorganotin (IV) with 2-thioacetic acid -5-phenyl-1,3,4-oxodiazole and benzamidophenyl alanine, Iran, J.Chem.Chem.Eng., 30, 67-72 (2011)
- Yousif E., Farina Y., Kasar K., Grasia A. and Ayid K., Complexes of 2-thioacetic acid benzothiazole with some metal ions, Am.J.Appl.Sci., 6(4), 582-585 (2009)
- Yousif E., Muaiad F. and Adil H., Synthesis and characterization 2-yl-sulfanyl)-acetic acid ligand, J.AL-NahrainUniv., 14(1), 44-49 (2011)
- Banger K.K., Duraj S.A., Fanwick P.E., Hehcmann D.G., Hepp A.F. and Mrtocle R.A., Synthsis and structural characterization of novel indium mercapto derivative [ClIn(SCH2(COO)2]2-[4-MePyH)2]2+, NASAITM,212289 (2004)
- Yousif E., Aliwi S.M., Ameer A.A. and Ukal J.R., Improved photostability of PVC films in the presence of 2-thioacetic acid -5-phenyl-1,3,4-oxodiazole complexes, Turk J.Chem., 33, 399-410 (2009)
- Buttrus N.H., AL-Smaan S.H. and AL-Asalli S.M., Mono, di-and tri-nuclear complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 1,4-bis(sodium thioglycolate) butane, International J. Chem., 20(1), 37-42 (2010)
- Gearvy W.J., The use conductivity measurements in organic solvents for characterization of coordination compounds, Coord.Chem.Rev., , 8-81 (1971)
- Deacon G.B. and Philips R.J. (1980), Thermal characteristic of Cu(II) carboxylates with fatty acid, Coord.Chem.Rev., 23, 227-238 (1980)
- Mostafa M., Metal Chelates of Hydrazone Ligand Chelating Tendencies of 2-carboxphenylhydrazoacetoacetanilide (2-Cphaaa) Ligand, Res.J.Chem.Sci., 1(7), 1-14 (2011)
- Mrinalini L. and Singh A.K.M., Mixed ligand coblt (III) complexes with 1-amidino-o-methylurea and amino acids,Res. J. Chem. Sci., 2(1), 45-49 (2012)
- Chaudhary R. and Shelly, Synthesis, spectral and pharmacological study of Cu(II),Ni(II) and Co(II) coordination complexes, Res. J. Chem. Sci., 1(15), 1- (2011)
- Bhatti M., Ali S., Huma F. and Shahazadi S., Organo tin (IV) derivatives of N-maleonyl amino acids, Their synthesis and structural elucidation, Turk J.Chem., 29, 463-470 (2005)
- AL-Allaf T.A.K. and Buttrus N.H. Coordination complexes of Uranium (VI),Thorium(IV),Cerium (III) and Lanthanum (III) with various multidentade ligands, ABATH AL-YAEMOK,,101-110, (1994)
- Nakamoto K., Infrared of inorganic and coordination compounds, 6th Edition, John Wiley New York (1997)
- Saleem H.S., Ramadadan A.A.T., Taha A. and Samy F.,Unreported coordination behavior of a squaric bis(hydrazine) ligand, Res. J.Chem. Sci., 1(4), 109-116 (2011)
- AL-Allaf T.A.K., Buttrus N.H. and Hitchcock P.B., Palladium and Platinum (II) complexes with arylthioethene, Asia.J. Chem.,9(2), 187-194 (1997)
- Hussein S.S., Mostafa M., Stefan S.L. and ABDEL-Aziz E., Structural diversity of 3d complexes of an isatinic quinolyl hydrazine, Res. J. Chem. Sci., 1(5), 67-72 (2011)
- Cotton F.A., Wilkinson G., Murillo C.A. and Bochmann M., AdvanceInorganic Chemistry, 6th Ed., Joh. Wiley and Sons, New York, 810-842 (1990)
- Buttrus N.H. and Saeed F.T.,Bis (N-methyl benzimidazolium-2-thio) ethane,propane or butane and its Co(II),Ni(II),Cu(II) and Zn(II) ionic salts, International J.Chem., 22(2),117-122 (2012)
- Mohamed A.A., Buttrus N.H. and Younis M.K., New complexes of polyurea with Cu(II), Mn(II) and Cr(II) (Synthesis and characterization, National J.Chem., 38, 333-348 (2010)