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Structural, Optical and Electrical Characteristics of Nanostructured ZnO thin Films with various Thicknesses deposited by RF Magnetron Sputtering

Author Affiliations

  • 1Department of Physics, Osmania University, Hyderabad, INDIA
  • 2 Department of Physics, Mahatma Gandhi University, Nalgonda AP, INDIA

Res. J. Physical Sci., Volume 1, Issue (6), Pages 17-23, July,4 (2013)

Abstract

Zinc oxide thin films having various thicknesses between 100 nm and 400 nm were deposited on glass substrates by RF magnetron sputtering technique. These films have been analyzed for their structural, optical and electrical properties as a function of the thickness by a series of characterization techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), resistivity measurements and spectrophotometer. The micro structural parameters, such as the lattice constant, crystallite size, stress and strain are calculated. All these films exhibited strong (002) diffraction peaks corresponding to hexagonal wurtzite structure. The visible range transmittance was found to be over 90%. The optical band gap increased from 3.21 eV to 3.37 eV and the electrical resistivity decreased from 5.21x10-2 Ω cm to 1.47x10-2 Ω cm with increase of film thickness.

References

  1. Mitra A.P. and Chatterjee H.S. Maiti, ZnO thin film sensor, Mater. Lett.35, 33–38 (1998)
  2. Jeong W.J., Kim S.K. and Park G.C., Preparation and characteristic of ZnO thin film for an application of solar cell, Thin Solid Films180, 506 (2006)
  3. Bagall D.M., Chen Y.F., Zhu Z., Yao T., Koyama S., Shen M.Y. and Goto T., Optically pumped lasing of ZnO at room temperature, Appl. Phys. Lett., 70, 2230 (1997)
  4. Srikant V., Valter S. and David R., Films on Sapphire: I, Effect of Substrate Orientation, J. Am. Ceram. Soc.,78, 1931 (1995)
  5. Amlouk, Touhari F., Belgacem S., Kamoun N., Barjon D., Bennaceur R., Structural and Acoustic Properties of ZnO Thin Films Prepared by Spray. Phys. Stat. Sol. (A), 163, 73–80 (1997)
  6. Pauporte T. and Lincot D., Electrodeposition of Semiconductors for Optoelectronic Devices: Results on Zinc Oxide, 'Electrochim. Acta,45, 3345 (2000)
  7. Sahu D.R., Studies on the properties of sputter-deposited Ag-doped ZnO films, Microelectron. J., 38, 1252 (2007)
  8. Morgan J.H. and Brodie D.E., The Preparation and Some Properties of Transparent Conducting ZnO for use in Solar Cells, Can. J. Phys.60, 1387 (1982)
  9. Paraguay F., Estrada D.W., Acosta L.D.R. and Andrade N.E., M.Miki-Youshida, Growth, structure and optical characterization of high quality. ZnO thin films obtained by spray pyrolysis, Thin Solid Films350, 192 (1999)
  10. Cui Y.G., Du G.T., Zhang Y.T., Zhu H.C. and Zhang B.L., J. Cryst. Growth,282, 389 (2005)
  11. Heo Y.W., Norton D.P. and Pearton S.J., Zinc Oxide Bulk, Thin Films and nanostructures .J. Appl. Phys., 98, 073502 (2006)
  12. Sun X.W. and Kwok H.S., J. Appl. Phys., 86, 408 (1999)
  13. Mridha S. and Basak D., .Effect of thickness on the structural, electrical and optical properties of ZnO films, Mater. Res. Bull.,42, 875 (2007)
  14. Fahoume M., Maghfoul O., Aggour M., Hartiti B., Chraibi F. and Ennaoni A., Growth and characterization of ZnO thin lms prepared by electrodeposition technique, Sol. Energy Mater. Sol. Cells,90, 1437–1444 (2006)
  15. Bhargava R., (Ed.), Properties of Wide Bandgap II–VI, Semiconductors, London, 1997
  16. Yoshino K., Hata T., Kakeno T., Komaki H., Yoneta M., Akaki Y. and Ikari T., Electrical and optical characterization of n-type ZnO thin lms, Phys. Stat. Sol.626–630 (2003)
  17. Harbeke G. (Ed.), Polycrystalline Semiconductors: Physical Properties and Applications, Berlin, 1985
  18. Vander A. Drift, Philips Res. Rep.,22, 267 (1967)
  19. V. Assunc¸a˜o, E. Fortunato, A. Marques, A. Gonc¸ alves, I.Ferreira, H. A guas, R. Martins, Thin Solid Films,442,121 (2003)
  20. Gupta V. and Mansingh A., J. Appl. Phys., 80, 1063–1073 (1996)
  21. Cullity B.D., Elements of X-ray Diffraction, second edition, Addison-Wesley, (1978)
  22. Minami T., Sato H., Takata S., Ogawa N. and Mouri T., Jpn. J. Appl. Phys., 3, L1106–L1109 (1992)
  23. Maniv S., Westwood W.D. and Colombini E., J. Vac. Sci. Technol.,20, 162 (1982)
  24. Bilgin V., Kose S., Atay F. and Akyur I., Mater. Chem. Phys.,94, 103-108 (2005)
  25. Seon J.B., Lee S., Kim J.M. and Jeong H.D., Chem. Mater.,21, 604-611 (2009)
  26. Ortuño López M.B., Valenzuela-Jáuregui J.J., SoteloLerma M., Mendoza- Galván A. and Ramirez-Bon R., Highly oriented CdS films deposited by an ammonia-free chemical bath method, Thin Solid Films429, 34- 39 (2003)
  27. Hur T.B., Hwang Y.H., Kim H.K., Lee I.J., Strain effects in ZnO thin films and nanoparticles, J. Appl. Phys.99, 064308 (2006)
  28. Patsalas P., Gravalidis C. and Logothetidis S., J. Appl. Phys., 96, 6234– 6246 (2004)
  29. Benger P.R., Chang K., Bhattacharya P., Singh J. and Bajaj K.K., Strain effects in ZnO thin films and nanoparticles, Appl. Phys. Lett.53, 684 (1988)
  30. Gupta V. and Mansingh A., Influence of post deposition annealing on the structural and Optical Properties of sputtered Zinc Oxide Film, J. Appl. Phys.80, 1063–1073 (1996)
  31. Chrysicopoulou P., Davazoglou D., Trapalis Chr. andKordas G., Characterization of TiO2/Polyelectrolyte Thin Film Fabricated by a Layer-by-Layer Self-Assembly Method, Thin Solid Films,323, 188 (1998)
  32. Mayadas A.F. and Shatzkes M., Electrical-resistivity model for polycrystalline films: the case of arbitrary reflection at external surfaces, Phys Rev B,1, 1382-9 (1970)